quantitative test for peroxides in organic solvents – Water Testing Blog & Water Test Kit Store http://watertestingblog.com "It's your water, your health.. and ultimately your LIFE!" Thu, 30 Dec 2021 07:33:30 +0000 en-US hourly 1 https://wordpress.org/?v=4.7.5 Quantitative Test for Peroxides in Organic Solvents http://watertestingblog.com/2008/07/29/quantitative-test-for-peroxides-in-organic-solvents/ http://watertestingblog.com/2008/07/29/quantitative-test-for-peroxides-in-organic-solvents/#respond Tue, 29 Jul 2008 13:32:00 +0000 http://watertestingblog.com/2008/07/29/quantitative-test-for-peroxides-in-organic-solvents/ A quantitative testing method for the presence of peroxides in organic solvents and ethers exists as well:


EM QuantR Peroxide Test, 0.5ppm to 25ppm

Note: The following instructions come from Galade Chemical, a distributor of the above product, and the authors of Water Testing Blog present them ‘as is’, with no expressed or implied guarantees of accuracy.

Volatile Ethers

Immerse a test strip for approximately 1 second in the solvent being tested and allow to evaporate.

Breathe on the reaction zone 4 times for 3-5 seconds each time. Alternatively, immerse briefly in distilled water.

Compare the reaction zone with the color scale.

Low Volatility Ethers

A. Immiscible with water.

Mix a sample of the ether to be tested with 3 times its volume of peroxide-free ether or petroleum benzine (boiling range 40-60°C).

Test as described under “Volatile ethers.”

Record the value indicated on the scale and multiply by 4.

B. Miscible with water

Mix a sample of the ether to be tested with 3 times its volume of distilled water.

Immerse a test strip for approximately 1 second.

Wait 2 minutes and compare with the color scale.

Convert the results as under “Conversion.”

Conversion

Allowing for dilution, 3mg/l on the color scale is equivalent to:

90mg/l tetrahydrofuran peroxide or 30mg/l peroxide calculated as H2O2

150mg/l dioxan peroxide or 45mg/l peroxide calculated as H2O2.

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