At this time the staff of Water Testing Blog does not know of a simple testing method for bromates. This does not mean companies who bottle water cannot have their product(s) tested for bromates.

“MWH Labs has received accreditation for testing of bromate by EPA Method 317 under the Stage 2 Disinfection/Disinfection Byproducts (DDBP) Rule. Method 317 is, a very accurate and very precise analytical method for bromate, that avoids many of the problems with false negatives and false positives that are associated with the existing analytical method (EPA 300.1). Additionally method 317 is capable of detecting bromate as low as 1 ppb (vs 5 ppb for method 300.1), helping clients to more accurately assess their bromate treatment options. Bromate is regulated in bottled water and potable water at a level of 10 ppb.”(source)

A while back the newspapers and television reports filled up with reports that some bottled water contained high levels of bromates and everyone agreed that bottled water ought not contain bromates. But how many of you ever stopped to ask where the bromates came from in the first place?

“Bromate is a chemical that is formed when ozone used to disinfect drinking water reacts with naturally occurring bromide found in source water. EPA has established the Stage 1 Disinfectants/Disinfection Byproducts Rule to regulate bromate at annual average of 10 parts per billion in drinking water. This standard will become effective for large public water systems by December 2001 and for small surface water and all ground public water systems in December 2003.” (source)

While oxidizers such as chlorine, bromine and chlorine dioxide do an excellent job of cleaning up water so that it contains no microorganisms and/or harmful strains of bacteria, their success as disinfectants does not come without a price.

Byproducts of the chemical reaction between the ‘bad’ components and the oxidizers form each time one of those ‘bad’ components gets eliminated and we call the disinfection byproducts. See below for a list of the ones listed in the National Primary Drinking Water Regulations for Disinfection ByProducts along with their MCL’s (Maximum Contaminat Levels) and potential hazards to humans:

• Bromate — Associated with an increased risk of cancer. Maximum Contaminant Level: 0.01 mg/L
• Chlorite — Associated with Anemia; infants and young children: nervous system effects. Maximum Contaminant Level: 1.0 mg/L
• Haloacetic acids (HAA5) — Associated with an increased risk of cancer. Maximum Contaminant Level: 0.06 mg/L
• Total Trihalomethanes (TTHMs) — Associated with liver, kidney or central nervous system problems; increased risk of cancer. Maximum Contaminant Level: 0.08 mg/L

The term biguanide refers to a sanitizer that uses a complex polymer as its base rather than traditional chlorine or bromine molecules. Use of a biguanide sanitizer elimiates the offensive ‘chemical smell in a pool/spa, puts a stop to the bleaching of hair and swimwear, reduces eye irritation and makes it possible for those with allergic reaction to chlorine or bromine to enjoy a dip in the pool/spa.

Mixing Biguanide With Chlorine/Bromine?

A definite no-no. The chlorine or bromine will destroy the biguanide polymer and in some cases cause insightly preciptates to fall out of solution. You will NOT enjoy cleaning up a pool or spa in which biguanides have met up with oxidizers such as chlorine or bromine.

Switching Between Biguanide and Chlorine/Bromine Sanitizers?

For those who seek to switch from a biguanide system to chlorine/bromine system, or vice versa, make certain you remove ALL of the former system’s chemicals before adding the new system’s chemicals.

In the case where a person wants to switch from a chlorine/bromine system over to a biguanide system, they should perform a test for Total Chlorine/Bromine before adding any of the biguanide chemicals. Test strips work well for this application and pool/spa owners can choose from a number of multi-parameter test strips to get the job done:

• Pool Check 6-in-1: free chlorine, total chlorine/bromine, pH, total alkalinity, total hardness, cyanuric acid
• Pool Check 5-in-1: free chlorine, total chlorine/bromine, pH, total alkalinity, total hardness
• Pool Check 4-in-1: free chlorine, total chlorine/bromine, pH, total alkalinity
• Pool Check Low Chlorine 3-in-1: free chlorine, pH, total alkalinity

And for those who REALLY want to make sure no chlorine resides in thei water, try using the WaterWorks^TM Ultra Low Total Chlorine Strips. Their lowest detection block starts at 0.005ppm total chlorine — an incredibly detection level for a dip and read test strip!

Per the request of several men and women currently serving in the United States Armed Forces and other branches of the Unites States Government, we will begin posting possible alternate products for popular (established) NSN’s (National Stock Numbers) related to water quality testing.

NSN: 6630010273914, 6630010440334, 6630010673827 — Chlorine, Bromine and pH Visual Test Kits

• WaterWorks and SenSafe Test Strips — Simple dip and read test strips for a wide range of parameters. Easier to use than wet kits, longer shelf lives, and much more convenient to carry.
• eXact EZ Water Quality Testing Meter — EPA Compliant (for free and total chlorine) handheld multi-parameter water quality testing meter. IP67 Waterproof rating.

Note: We have found that the products suggested above meet or exceed the specifications of the original NSN (National Stock Number) item. This does not mean, though, that you may substitute them in place of the item on a Government Contract. We provided the above information as possible sources of water quality testing products for consideration in future Contracts/Bids only.